The use of sulfur ylides in the synthesis of substituted indoles.
نویسندگان
چکیده
[reaction: see text] This letter describes the insertion of rhodium carbenoids into thioindoles. C-10 thioindoles undergo fragmentation-coupling reactions when exposed to rhodium carbenoids. In an analogous fashion, ketoester- and malonate-substituted carbenoids have been found to insert into C-2 thioindoles. In contrast, vinylogous carbenoids were found to alkylate C-2 thioindoles at C-3.
منابع مشابه
[BMIm]HSO4 as a Green and Highly Efficient Catalyst for One-pot Synthesis of 3-Substituted Indoles under Ultrasound Irradiation
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ورودعنوان ژورنال:
- Organic letters
دوره 3 15 شماره
صفحات -
تاریخ انتشار 2001